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Getting Black Spots Off Rims



Hey all. I'm not new to Adams stuff, but I haven't really posted here that much. I just got my car washed for the first time in a while. The temperatures over here have been well below freezing for a very VERY long time, and today we finally hit 60 degrees :D 


After I cleaned my car, and the wheels, I noticed black spots on the wheels that just won't come off. The bulk of the grime and break dust came off, but there are spots on the wheels that are much more stubborn. I can feel them with my finger nail, but they won't budge. What are these black spots and how can I get them off? I used detail spray, and a rim cleaner and neither worked. I haven't tried Adams wheel cleaner yet, but decided to post it here to get some insight from those much more knowledgable and experience than me before I buy anything. 


Thanks! And here are some pics of what I'm talking about. 





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